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气溶胶辅助化学气相沉积制备Al掺杂ZnO透明导电薄膜

Fabrication of Transparent Conductive Al-doped ZnO Thin Films by Aerosol-assisted Chemical Vapour Deposition

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【作者】 秦秀娟韩司慧智赵琳左华通宋士涛

【Author】 QIN Xiu-Juan1,2,HAN Si-Hui-Zhi1,ZHAO Lin1,ZUO Hua-Tong1,SONG Shi-Tao3(1.College of Environmental and Chemical Engineering,Yanshan University,Qinhuangdao 066004,China;2.State Key Labora-tory of Metastable Materials Science and Technology,Qinhuangdao 066004,China;3.College of Physics and Chemistry,Hebei Normal University of Science and Technology,Qinhuangdao 066004,China)

【机构】 燕山大学环境与化学工程学院亚稳材料制备技术与科学国家重点实验室河北科技师范学院理学院

【摘要】 采用气溶胶辅助化学气相沉积(AACVD)法在玻璃衬底上制备了Al掺杂ZnO(AZO)薄膜.研究了Al掺杂(2at%~8at%)对ZnO薄膜结构及光电性能的影响.利用XRD、SEM、EDAX、紫外可见分光光度计等手段对样品进行测试.结果表明,制备的所有AZO薄膜均具有纤锌矿结构,不具有沿c轴方向的择优取向,XRD图谱中未观察出Al的相关分相.在可见光范围内,AZO薄膜的平均透过率大于72%,光学禁带宽度随Al掺杂量的增加而变窄.同时根据四探针技术所得的数据得知:Al的掺杂导致薄膜方块电阻的变化,随着Al掺杂量的增加,方块电阻有明显变小的现象,掺杂6at%Al的AZO薄膜具有最低方块电阻(18Ω/□).

【Abstract】 Al-doped ZnO thin films were prepared by aerosol-assisted chemical vapour deposition(AACVD) on glass substrates.The effect of Al content(2at%-8at%) on the structural,optical and electrical properties of Al-doped ZnO thin films was investigated in detail.The samples were tested by XRD,SEM,EDAX and UV-Vis spectrophotometer.The results indicate that the AZO films have a hexagonal(wurtzite) structure without preferen-tial orientation along c-axis,and however no Al related phases are observed.The average transmittances of the AZO film is over 72% in the visible regions.The optical band gap for the AZO films becomes narrow with the increasing Al dopant.The four-point probe technique is used to characterize thin films electrically.The data shows that Al dopant decrease the sheet resistance.The ZnO films doped with 6at% Al exhibit a minimum of sheet resistance(18Ω/□).

【基金】 河北省自然科学基金(B2008000758)~~
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2011年06期
  • 【分类号】O484.1
  • 【被引频次】23
  • 【下载频次】429
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