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气溶胶辅助化学气相沉积制备Al掺杂ZnO透明导电薄膜
Fabrication of Transparent Conductive Al-doped ZnO Thin Films by Aerosol-assisted Chemical Vapour Deposition
【摘要】 采用气溶胶辅助化学气相沉积(AACVD)法在玻璃衬底上制备了Al掺杂ZnO(AZO)薄膜.研究了Al掺杂(2at%~8at%)对ZnO薄膜结构及光电性能的影响.利用XRD、SEM、EDAX、紫外可见分光光度计等手段对样品进行测试.结果表明,制备的所有AZO薄膜均具有纤锌矿结构,不具有沿c轴方向的择优取向,XRD图谱中未观察出Al的相关分相.在可见光范围内,AZO薄膜的平均透过率大于72%,光学禁带宽度随Al掺杂量的增加而变窄.同时根据四探针技术所得的数据得知:Al的掺杂导致薄膜方块电阻的变化,随着Al掺杂量的增加,方块电阻有明显变小的现象,掺杂6at%Al的AZO薄膜具有最低方块电阻(18Ω/□).
【Abstract】 Al-doped ZnO thin films were prepared by aerosol-assisted chemical vapour deposition(AACVD) on glass substrates.The effect of Al content(2at%-8at%) on the structural,optical and electrical properties of Al-doped ZnO thin films was investigated in detail.The samples were tested by XRD,SEM,EDAX and UV-Vis spectrophotometer.The results indicate that the AZO films have a hexagonal(wurtzite) structure without preferen-tial orientation along c-axis,and however no Al related phases are observed.The average transmittances of the AZO film is over 72% in the visible regions.The optical band gap for the AZO films becomes narrow with the increasing Al dopant.The four-point probe technique is used to characterize thin films electrically.The data shows that Al dopant decrease the sheet resistance.The ZnO films doped with 6at% Al exhibit a minimum of sheet resistance(18Ω/□).
【Key words】 aerosol; chemical vapour deposition; Al-doped ZnO; transparent conductive thin films;
- 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2011年06期
- 【分类号】O484.1
- 【被引频次】23
- 【下载频次】429