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微粉微晶玻璃的致密烧结与析晶
Studying about Densification by Sintered and Crystallization of Tiny Powder Glass-Ceramics
【摘要】 采用R2O-CaO-MgO-Al2O3-SiO2系统,制备微粉微晶玻璃.研究合理的烧结、析晶温度制度,以及升温速率、粉体粒度对玻璃析晶、显微结构的影响,探讨提高微晶玻璃的晶体质量分数和致密度、优化微晶玻璃显微结构的途径.结果表明,采用微粉制备辉石族矿物为主晶相微晶玻璃时,粉体的巨大表面积使微晶化进程变得更加容易,晶化处理时间大大缩短.此外,粉体颗粒度的减小,有利于微晶化的充分进行和微晶玻璃显微结构的致密化.
【Abstract】 Glass ceramics have been made from tiny glass powders of R2O-CaO-MgO-Al2O3-SiO2.Temperature-time schedule for sinter and crystallization was studyed.Influence of heating-up rate and particle size on the crystallization and microstructure of glass were investigated.Methods of increasing degree of densification and crystallization volume,and ways of improving microstructure of glass-ceramics were discussed.The results showed that during the process of making tiny glass powder into pyroxene glass-ceramics,huge surface area of powder brought about crystallization easily,which shorted the shorten crystallization time,and improved the microstructures of the glass-ceramics.
【Key words】 tiny powder glass-ceramics; density sinter; crystallization; heating-up rate; particle size;
- 【文献出处】 华侨大学学报(自然科学版) ,Journal of Huaqiao University(Natural Science) , 编辑部邮箱 ,2011年01期
- 【分类号】TQ171.1
- 【被引频次】10
- 【下载频次】366