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活性炭纤维(ACF)吸附二硫化碳(CS2)的研究

The adsorption of carbon disulfide on activated carbon fibers

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【作者】 谢遵园李军平赵宁王峰彭伟才毛博阳肖福魁魏伟孙予罕

【Author】 XIE Zun-yuan1,2,LI Jun-ping1,ZHAO Ning1,WANG Feng1,PENG Wei-cai1,Mao Bo-yang3,XIAO Fu-kui1,WEI Wei1,SUN Yu-han1(1. State Key Laboratory of Coal Chemistry,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China;2. Graduate University of the Chinese Academy of Sciences,Beijing 100049,China;3. Department of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China)

【机构】 中科院山西煤炭化学研究所煤转化国家重点实验室中国科学院研究生院北京化工大学材料科学与工程学院

【摘要】 研究了商用活性炭纤维(Activated carbonf fiber-ACF)对二硫化碳(Carbon disulfide-CS2)的吸附性能,并与活性炭(Activated carbon-AC)、沸石吸附CS2的性能做了对比。重点考察了CS2浓度、吸附气流量、湿度和ACF含水量对CS2在ACF上吸附性能的影响。结果表明:相对于AC、沸石,ACF对CS2的吸附快、吸附率高,达46.5%;CS2浓度、吸附气流量增加,穿透点前移;湿度和含水量上升会明显降低ACF对CS2的吸附性能,当湿度升至65%时,吸附时间缩短28.6%;当含水量为质量分数45%时,穿透时间提前42.9%;当含水量增至质量分数60%时,CS2迅速穿透,ACF几乎不能再吸附CS2。

【Abstract】 The adsorptive performance of commercial activated carbon fiber(ACF) for CS2 was investigated and a comparison of the adsorptive performance of ACF with activated carbon(AC) and zeolites was made.The effects of the operating parameters such as CS2 concentration,flux,humidity and water content in ACF on the adsorptive performance were investigated.Results indicated that the ACF had a higher adsorption capacity of 46.5% than AC and zeolites did toward CS2.The breakthrough time decreased greatly with flow rate and CS2 concentration.The adsorptive performance deteriorated with increasing humidity and water content in the ACF.The adsorption time was shortened by 28.6% when humidity was increased to 65%.The breakthrough time was decreased by 42.9% when water content in the ACF was increased to 45%.The adsorptive capacity was negligible when water content in the ACF was increased to over 60%.

【基金】 国家青年自然科学基金(20803089)~~
  • 【文献出处】 新型炭材料 ,New Carbon Materials , 编辑部邮箱 ,2009年03期
  • 【分类号】TB332
  • 【被引频次】17
  • 【下载频次】538
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