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耐高温TTOA-环氧树脂的合成及表征

Synthesis and Charaterization of Heat Resistant TTOA-Epoxy Resin

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【作者】 刘志雄; 王小华; 邹晓勇; 高峰;

【Author】 Liu Zhixiong,Wang Xiaohua,Zhou Xiaoyong,Gao Feng(College of Chemistry and Chemical Engineering,Jishou University,Jishou,Hunan 416000,China)

【机构】 吉首大学化学化工学院;

【摘要】 以桐油酸酐(TOA)和三(2-羟乙基)异氰脲酸酯(THEIC)为原料,合成了赛克-桐油酸酐(TTOA)固化剂,然后用TTOA固化环氧树脂E44得到TTOA-E44树脂。TTOA-E44树脂的热差分析(TGA)的实验结果表明:固化树脂的耐热指数高达174℃,表观分解温度高达356℃,抗热老化性能和弯曲强度优于同类固化剂的固化物。

【Abstract】 A curing agent of TTOA with excellent thermal property was synthesized from eleostearic acid anhydride and tri(2-hydroxyethyl) isocyanurate,which was used to cure the E44 epoxy resin forming TTOA-E44 resin.The findings of TGA analysis showed that the heat-resistant index of TTOA-E44 resin has up to 174 ℃ and the apparent decomposition temperature over 356 ℃.Its thermal ageing property and bending strength was better than other similar products.

  • 【文献出处】 涂料工业 ,Paint & Coatings Industry , 编辑部邮箱 ,2009年10期
  • 【分类号】TQ323.5
  • 【被引频次】5
  • 【下载频次】213
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