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树枝状荧光探针设计制备及荧光特性初步研究

Preliminary Study on Preparation and Fluorescent Characteristic of the Dendritic Fluorescent Probe

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【作者】 兰云泉费学宁张宝莲石斌周立峰

【Author】 LAN Yun-quan,FEI Xue-ning,ZHANG Bao-lian,SHI Bin,ZHOU Li-feng(Department of Materials Science and Engineering,TIUC,Tianjin 300384,China)

【机构】 天津城市建设学院材料科学与工程系

【摘要】 树枝状荧光探针是将荧光染料引入树枝状化合物(dendrimer)端基的一类化合物,具有良好的稳定性及光谱特性.笔者以2,2-二甲氧基乙胺为核,采用发散合成法合成了一端含活性氨基的扇形树枝状化合物,并将羧基噻唑橙染料(TO-COOH)引入树枝状化合物的端基,制备出树枝状荧光分子.初步研究了其荧光特性,讨论了反应温度、反应时间等条件对反应收率的影响.

【Abstract】 As a kind of compound prepared by applying fluorescent dye to the terminal of dendrimer,the dendritic fluorescent probe takes on favorable photostability and excellent spectrum characteristics.The author of this paper firstly synthesizes a kind of fan-shaped dendrimer with 2,2-dimethoxyethyeneamine as its core by a divergent method,and then prepares dendritic fluorescent molecules by applying fluorescent dye /(thiazole orange molecule) to the dendrimer’s active terminal,finally does a preliminary study on the dendritic fluorescent probe’s fluorescent characteristic,and discusses the effect of such conditions as the reaction temperature and time on the yield of the reaction.

【基金】 国家自然科学基金(20772090);天津科委重点项目(08JCZDJC18200)
  • 【文献出处】 天津城市建设学院学报 ,Journal of Tianjin Institute of Urban Construction , 编辑部邮箱 ,2009年03期
  • 【分类号】TH773
  • 【下载频次】178
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