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阴极扩散层结构对空气自呼吸式DMFC性能的影响

Effect of cathode gas diffusion layers on air-breath direct methanol fuel cell

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【作者】 高妍孙公权王素力赵钢刘冲

【Author】 GAO Yan1,2,SUN Gong-quan1,WANG Su-li1,ZHAO Gang1,LIU Chong3 (1. Dalian Institute of Chemical Physics,Chinese Academy of Science,Dalian Liaoning 116023,China;2.Graduate School of the Chinese Academy of Sciences,Beijing 100039,China; 3. Dalian University of Technology,Dalian Liaoning 116023,China )

【机构】 中国科学院大连化学物理研究所中国科学院研究生院大连理工大学

【摘要】 采用三种碳粉制备了阴极扩散层,对其表面形貌、孔隙率、透水压和透气性进行了表征,并将其应用于空气自呼吸式直接甲醇燃料电池。结果表明,与Vulcan XC-72R和Black Pearls2000碳粉所制备的阴极扩散层相比较,采用Printex XE-2碳粉制备的阴极扩散层具有较高的孔隙率和适中的孔径,具有较高的透气性和较低的透水压,有利于阴极气体扩散和水的排出,提高了空气自呼吸式直接甲醇燃料电池的性能和极限电流密度。

【Abstract】 The effect of cathode gas diffusion layers (GDLs) on air-breath direct methanol fuel cell(DMFC)was studied. Three types of carbon powders (Vulcan XC-72R,Printex XE-2 and Black Pearls 2000) were used as cathode gas diffusion layers,which were characterized by N2 adsorption-desorption isotherms and scanning electron microscope (SEM). The porosity,gas permeability and water permeation pressure of three GDLs were tested. It is shown that the Printex XE-2 GDL had the proper porosity and mass transport ability,which resulted in a higher cell performance than that of Vulcan XC-72R and Black Pearls 2000.

【基金】 “863”国家自然科学基金项目(2006AA05Z137);微纳米技术及系统辽宁省重点实验室和微系统与微制造辽宁省级高校重点实验室开放基金资助(20776139)
  • 【文献出处】 电源技术 ,Chinese Journal of Power Sources , 编辑部邮箱 ,2009年08期
  • 【分类号】TM911.4
  • 【下载频次】173
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