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铝(Ⅲ)在乳状液膜体系中的迁移行为

Transfer Behavior of Aluminium(Ⅲ) through Emulsion Liquid Membrane System

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【作者】 谭海燕; 杨雯雁; 王孝华; 陆俭洁; 柳畅先;

【Author】 Tan Haiyan,Yang Wenyan,Wang Xiaohua,Lu Jianjie,Liu Changxian(Key Laboratory of Analysical Chemistry of the State Ethnic Affair Commission,College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan 430074,China)

【机构】 中南民族大学化学与材料科学学院分析化学国家民委重点实验室;

【摘要】 研究了铝()在乳状液膜分离体系中的迁移行为.确立了最佳迁移条件:制乳搅拌速度2400 r/min,制乳时间10 min,乳液与外相溶液混合时间15 min,乳水比0.4,磷酸三丁酯(TBP)浓度4.5%,span80和液体石蜡浓度均为7.9%,内相和外相HCl浓度分别为1.0 mol/L和3.0 mol/L.在此条件下,铝()的迁移率达90%以上.

【Abstract】 The transfer behavior of aluminium(Ⅲ) through the following emulsion liquid membrane system was studied.The optimum conditions established were as follow: The stirring speed for emulsification was 2 400 r/min,the emulsifing time was 10 min,the mixing time of the emulsion and external phase solution was 15 min,the ratio of emulsion to water was 0.4,the concentrations of tributylphosphate(TBP) was 4.5 %,span80 and paraffin were both 7.9 % and HCl in the internal and external phases were 1.0 mol/L and 3.0 mol/L respectively.Under the conditions,the transfer of aluminium(Ⅲ) was > 90 %.

【关键词】 铝(Ⅲ); 乳状液膜; 分离;
【Key words】 aluminium(Ⅲ); emulsion liquid membrane; separation;
  • 【文献出处】 中南民族大学学报(自然科学版) ,Journal of South-Central University for Nationalities(Natural Science Edition) , 编辑部邮箱 ,2008年03期
  • 【分类号】TQ028
  • 【下载频次】46
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