节点文献

新型木质素季铵盐絮凝剂的合成与絮凝性能

Synthesis and Flocculation Performance of a New Quaternary Ammonium Salt of Lignin

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 杨爱丽高伟魏文韫蒋文举

【Author】 YANG Ai-li~* GAO Wei WEI Wen-yun JIANG Wen-ju (College of Architecture and Environment,Sichuan University,Chengdu,Sichuan Province,610065)

【机构】 四川大学建筑与环境学院

【摘要】 以碱木质素和二甲基二烯丙基氯化铵(DMDAAC)为原料,通过接枝共聚反应制备了新型阳离子木质素季铵盐絮凝剂(QL),并确定了最佳合成工艺条件,同时采用红外光谱对产物结构进行了表征。实验结果表明,QL对4种模拟染料废水的脱色率均达92%以上。通过比较QL与阴离子型木质素的絮凝效果以及对絮体微观形貌的表征,初步探讨了QL的絮凝机理。

【Abstract】 A cationic quaternary ammonium salt of lignin flocculant QL was synthesized by graft copolymerization with alkaline lignin and N, N-dimethyldiallyl ammonium chloride (DMDAAC) as raw materials.The synthesized conditions were optimized. QL and lignin were charac- terized by Fourier Transform Infrared Spectroscopy (FT-IR).The molecular weights of lignin and QL were measured.The results of applying QL to the simulated dye wastewater showed that the decolorizing rate was up to above 92%.The microstructures of lignin flocs and QL flocs were characterized by the scanning electron microscopy (SEM).Results indicated that QL has favorable flocculation performance,and the flocculation mechanisms are charge neutralization and absorption bridging.

  • 【文献出处】 中国造纸学报 ,Transactions of China Pulp and Paper , 编辑部邮箱 ,2008年02期
  • 【分类号】X703.5
  • 【被引频次】25
  • 【下载频次】472
节点文献中: