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Magnetic properties of La-Zn substituted Sr-hexaferrites by self-propagation high-temperature synthesis

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【作者】 游李顺乔梁郑精武蒋梅燕姜力强盛嘉伟

【Author】 YOU Lishun, QIAO Liang , ZHENG Jingwu, JIANG Meiyan, JIANG Liqiang, SHENG Jiawei (College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China)

【机构】 College of Chemical Engineering and Materials Science Zhejiang University of TechnologyCollege of Chemical Engineering and Materials ScienceZhejiang University of TechnologyHangzhou 310014China

【摘要】 The La-Zn substituted SrM-type ferrites with the composition of Sr1-xLaxFe12-xZnxO19 (x=0-0.4) were prepared by self-propagating high-temperature synthesis (SHS). The single SrM phase was detected by XRD in the as-received samples by controlling the Fe contents in the reagents. The substitution of La3+ and Zn2+ obviously increased the magnetic properties of the as-prepared samples. The maximum im- provements of Br, Hcb and (BH)m were 14.4%, 15.3% and 30.7%, respectively compared with that of the samples without La-Zn substitution. Microstructure observation by SEM showed that the SHS method benefited forming the better particle features and achieving the higher Hcj in comparison with the traditional firing method.

【Abstract】 The La-Zn substituted SrM-type ferrites with the composition of Sr1-xLaxFe12-xZnxO19 (x=0–0.4) were prepared by self-propagating high-temperature synthesis (SHS). The single SrM phase was detected by XRD in the as-received samples by controlling the Fe contents in the reagents. The substitution of La3+ and Zn2+ obviously increased the magnetic properties of the as-prepared samples. The maximum im- provements of Br, Hcb and (BH)m were 14.4%, 15.3% and 30.7%, respectively compared with that of the samples without La-Zn substitution. Microstructure observation by SEM showed that the SHS method benefited forming the better particle features and achieving the higher Hcj in comparison with the traditional firing method.

【基金】 Project supported by the Key Project for Science and Technology of Zhejiang Province
  • 【文献出处】 Journal of Rare Earths ,稀土学报(英文版) , 编辑部邮箱 ,2008年01期
  • 【分类号】TG115
  • 【被引频次】23
  • 【下载频次】59
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