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木薯淀粉-VAc接枝共聚生物降解材料性能的研究

Study on Property of VAc-g-Cassava Starch Graft Copolymer

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【作者】 林华全正武符新

【Author】 LIN Hua~1,QUAN Zheng-wu~1,FU Xin~2 (1.College of Sci.and Eng.,South China University of Tropic Agriculture,Danzhou 571737,China; 2.College of Mechano-electronic & Information Eng.,South China University of Tropic Agriculture danzhou 571737,China)

【机构】 华南热带农业大学理工学院华南热带农业大学机电与信息工程学院

【摘要】 以过硫酸铵为引发剂,接枝聚合制成木薯淀粉-醋酸乙烯酯(VAc)接枝共聚物。将该共聚物增塑、交联处理,制备可生物降解材料;研究了此材料的力学性能、热性能及生物降解性能等。结果表明,木薯淀粉-VAc接枝共聚降解材料的拉伸强度、撕裂强度及断裂伸长率分别为23.29 MPa、89.48 kN/m及225%,实验室微生物及土埋方式能快速地促进材料降解,材料60 d内的最大失重率为55.68%。

【Abstract】 With ammonium persulfate as initiator,andvinylacetate(VAc)-g-cassava starch copolymer was synthesized by means of graft copolymerization.Biological degradable materials were prepared by means of plasticizing and crosslinking of the copolymer.The mechanical properties,thermal property and biodegradability of the biological degradable materials were studied.The results showed the tensile strength,tear strength and elongation at break of the biological degradable materials were 23.29MPa、89.48 KN/m and 225%respectively.A-amylase had excellent degrading effect on the grafted copolymer,bacillus and burying with clay could also speed up the degradation of the copolymer.The greatest weight loss rate of the copolymer was 55.68%after 60 days degradating.

  • 【文献出处】 塑料工业 ,China Plastics Industry , 编辑部邮箱 ,2008年S1期
  • 【分类号】TQ320.7
  • 【被引频次】3
  • 【下载频次】152
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