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水溶性双酚A型环氧树脂乳液的制备

Preparation of waterborne bisphenol-A epoxy resin emulsion

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【作者】 张道洪周继亮刘娜

【Author】 Zhang Dao-hong,Zhou Ji-liang,Liu Na (Co-founded key Laboratory of Catalysis and Materials Science by the State Ethnic Affairs Commission,Ministry of Education and Hubei Province,South-central University for Nationalities,Wuhan,Hubei 430074,China)

【机构】 中南民族大学催化材料科学湖北省暨国家民委-教育部共建重点实验室中南民族大学催化材料科学湖北省暨国家民委-教育部共建重点实验室 湖北武汉430074湖北武汉430074

【摘要】 采用E-Ⅱ型乳化剂和相反转技术制备水溶性双酚A型环氧树脂乳液,研究了乳化剂的用量、乳化时间、搅拌速率和乳化温度对乳液稳定性的影响。得出了最佳乳化工艺条件:乳化剂质量分数为7.25%~8.0%、乳化温度为60~70℃、搅拌速度为700~900 r/min、乳化时间为40~50 min。采用激光粒度衍射分析仪表征了水溶性环氧乳液的粒径为400~500 nm。

【Abstract】 Using self-synthesized E-Ⅱemulsifier the waterborne bisphenol-A epoxy resin emulsion was prepared by phase inversion technology.Effect of emulsification temperature,emulsification time,emulsifier concentration and shear rate on the stability of prepared waterborne bisphenol-A epoxy resin emulsion was discussed and analyzed.The optimum preparation condition of the waterborne bisphenol-A epoxy resin emulsion are as follows:emulsification temperature of 60~70 ℃,emulsification time of 40~50 min,emulsifier concentration of 7.25%~8.0% and the shear rate of 700~900 r/min.And the particle diameter of the waterborne bisphenol-A epoxy resin emulsion was about 400~500 nm from laser diffraction particle size analyzer.

【关键词】 环氧树脂水溶性乳液粒径制备
【Key words】 epoxy resinwaterborneemulsionparticle diameterpreparation
【基金】 中南民族大学自然科学基金资助项目(YZZ06012)
  • 【文献出处】 粘接 ,Adhesion in China , 编辑部邮箱 ,2008年02期
  • 【分类号】TQ430.1
  • 【被引频次】11
  • 【下载频次】620
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