【摘要】 文章研究了30%的双氧水在不同pH、溶剂、温度和催化剂条件下氧化异佛尔酮为2,3-氧化异佛尔酮的反应,同时优化出了后者分别在浓盐酸或硫酸作用下水解得到烟酮的最佳条件。该合成方法收率比文献报道有所提高。更多还原

【Abstract】 The oxidation reaction of isophorone with 30 % H2O2 to 2,3-epoxyisophorone was investigated by changing the pH,solvent,temperature and catalyst.Meantime,the hydrolysis of 2,3-epoxyisophorone to tobacco ketone was studied.The yields for two steps were enhanced,comparing with the reported method.更多还原