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利用冶金高炉渣制备微晶玻璃的研究

Preparation of Sintered Glass-ceramics from Blast Furnace Slag

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【作者】 卢红霞; 张伟; 李利剑; 关绍康; 张锐;

【Author】 LU Hong-xia1,2,ZHANG Wei3,LI Li-jian1,GUAN Shao-kang1,ZHANG Rui2(1.Postdoctoral Working Station of Angang Group,Anyang 455004,China;2.Postdoctoral Research Station of Material Science and Engineering,Zhengzhou University,Zhengzhou 450001,China;3.School of physics,Zhengzhou University,Zhengzhou 450001,China)

【机构】 安阳钢铁集团公司博士后工作站; 郑州大学物理工程学院; 郑州大学材料科学与工程博士后流动站; 郑州大学材料科学与工程博士后流动站 河南安阳455004; 河南郑州450001; 河南安阳455004;

【摘要】 利用X荧光、X-ray和DTA等技术分析高炉渣原料的成分、晶相组成和热学性能,并以冶金高炉渣为主要原料添加少量长石,通过较简单的烧结法制备出CaO-Al2O3-SiO2-MgO 4元系为基础的微晶玻璃,测试分析炉渣微晶玻璃的性能.结果表明,炉渣微晶玻璃晶相主要为钙黄长石,样品的吸水率为0.1%,维氏硬度为5~6 GPa,三点弯曲强度为60~70 MPa,其性能明显优于黏土砖.

【Abstract】 The crystal phases,chemical composition and thermal performance of slag were studied by X-ray fluorescence spectrometry,X-ray diffraction and DTA.Slag with other additives for the production of CaO-Al2O3SiO2-MgO system glass-ceramics by sintering was obtained.As-received glass-ceramics are investigated.The results showed that the main phase of the glass-ceramics is gehlenite.The as-received glass-ceramics also show better mechanics properties and lower water absorbtion than that of clay brick.A reasonable explanation for comprehensive utilization of slag was discussed in this paper.

【关键词】 炉渣; 微晶玻璃; 烧结法; 晶化处理;
【Key words】 slag; glass-ceramic; sintering; crystallization;
【基金】 中国博士后科研基金资助项目(20060400790)
  • 【文献出处】 郑州大学学报(工学版) ,Journal of Zhengzhou University(Engineering Science) , 编辑部邮箱 ,2007年03期
  • 【分类号】TQ171.1
  • 【被引频次】27
  • 【下载频次】413
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