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N掺杂可见光化催化剂的研究

N-doped Visible Light Responsive Photocatalysts

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【作者】 孙秀云; 李欣; 段传玲; 李健生; 王连军;

【Author】 SUN Xiu-Yun LI Xin DUAN Chuan-Ling LI Jian-Sheng WANG Lian-Jun (School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094)

【机构】 南京理工大学化工学院; 南京理工大学化工学院 南京210094; 南京210094;

【摘要】 The N-doped, yellow colored titanium oxide photocatalysts were prepared with Ti(SO4)2 and NH4HCO3 as precursors by precipitation method. The photocatalytic ability under the irradiation of UV or visible light for the catalysts prepared was studied by degradation of styphnic acid. The materials were characterized by EDS, XRD, FTIR, UV-Vis DRS, and XPS. The results indicate that the photocatalytic ability of catalysts is improved, especially the ability of visible light response. The results of UV-Vis DRS show that the response wavelength range of N-dopped nitrogen is red shifted, the absorption region is expanded to 476 nm.

【Abstract】 The N-doped, yellow colored titanium oxide photocatalysts were prepared with Ti(SO4)2 and NH4HCO3 as precursors by precipitation method. The photocatalytic ability under the irradiation of UV or visible light for the catalysts prepared was studied by degradation of styphnic acid. The materials were characterized by EDS, XRD, FTIR, UV-Vis DRS, and XPS. The results indicate that the photocatalytic ability of catalysts is improved, especially the ability of visible light response. The results of UV-Vis DRS show that the response wavelength range of N-dopped nitrogen is red shifted, the absorption region is expanded to 476 nm.

【关键词】 N掺杂; 光催化; 可见光; 斯蒂酚酸;
【Key words】 N-doped; photocatalytic; visible light; styphnic acid;
【基金】 江苏省省级环保科技项目(No.2005005);南京理工大学科研发展基金(No.XKF05012)资助项目
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2007年03期
  • 【分类号】O643.36
  • 【被引频次】16
  • 【下载频次】304
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