【摘要】 合成了2,2-二苯基-2-羟基乙酸苯胺加合物(1),其结构经UV,IR和X-射线单晶衍射仪表征。1的分子式为C34H31NO6,分子量为549.60,晶体属于三斜晶系,P1空间群,晶胞系数为:a=8.646(16),b=13.357(2),c=14.117(3),α=69.685(3)°,β=77.593(3)°,γ=71.748(3)°,V=1.441 3(5)nm3,Z=2,Dr=1.266 mg.cm-3,F(000)=580,μ(Mo Kα)=0.087 mm-1。结构由直接法解出,最终偏离因子为R1=0.054 6,wR=0.123 3。1通过分子间氢键连接形成超分子化合物。更多还原

【Abstract】 A novel 2,2-diphenyl-2-hydroxyactic acid and aniline adduct(1) was synthesized.Its composition and structure were characterized by UV,IR and x-ray single crystal diffraction.The results showed that 1(C34H31NO6)belongs to triclinic system and space group P1,with unit cell constants a=8.646(16) ,b=13.357(2) ,c=14.117(3) ,α=69.685(3)°,β=77.593(3)°,γ=71.748(3)°,V=1441.3(5) nm3,Z=2,Dr=1.266 mg·cm-3,F(000)=580,μ(MoKα)=0.087 mm-1,R1=0.054 6,wR2=0.123 3.The supermolecular structure was formed by hydrogen bond between molecules of 1.更多还原