【摘要】 研究了苏丹红Ⅰ、苏丹红Ⅲ和苏丹红Ⅳ在非极性溶剂石油醚和极性溶剂乙腈及乙腈-水混合溶液中的紫外-可见光谱特征。在极性溶剂中苏丹红系列的可见区特征吸收峰比在非极性溶液中略有红移;在乙腈-水混合溶液中,苏丹红Ⅰ的特征吸收峰比在乙腈溶剂中红移,最大红移达13nm,吸收强度最大增幅为34.5%;苏丹红Ⅲ的特征吸收峰红移8nm,吸收强度增幅为11%;苏丹红Ⅳ的特征吸收峰先红移后蓝移,吸收强度增幅数仅为2.5%。造成这一变化的原因是在乙腈-水混合溶液中,苏丹红Ⅰ,Ⅲ,Ⅳ分子内氢键被破坏,扩大了π键离域范围所致。更多还原

【Abstract】 The UV-Vis spectroscopic characterization of Sudan Ⅰ, Sudan Ⅲ and Sudan Ⅳ in nonpolar solvent ligarine, polar solvent acetonitrile, and acetonitrile-water mixture was studied. The characteristic absorption peaks of sudan series were a little red shifted in polar solvent compared to that in nonpolar solvent. In acetonitrile-water mixture the red shift of characteristic absorption peaks of sudan Ⅰ and sudan Ⅲ is respectively 13 and 8 nm, but the characteristic absorption peaks of sudan Ⅳ are red shifted before blue shifted. The increased adsorption strength of Sudan Ⅰ, Sudan Ⅲ and Sudan Ⅳ is 34.5%, 11% and 2.5% respectively. For these, the important reason is that the destroyed intramolecular hydrogen bond in Sudan series enlarges the scope of the π delocalized bond in polar solvent.更多还原