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A cluster line approach to finding new Fe-B-Y-Nb-Zr bulk metallic glasses

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【作者】 Nigel Pemberton-Pigott

【Author】 Nigel Pemberton-Pigott1), Qing Wang1), Weirong Chen1,2), Qingyu Zhang1), Jiang Wu1), Yanhui Li1), Jianbing Qiang1), Chuang Dong1,3) 1) State Key Laboratory of Materials Modification, Dalian University of Technology, Dalian 116024, China 2) Department of Mechanical Engineering, Dalian University, Dalian 116622, China 3) International Center for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, China

【机构】 State Key Laboratory of Materials Modification Dalian University of TechnologyDalian 116024 China

【摘要】 The glass forming ability of the [(Fe12/13Y1/13)100?xBx]96Nb2Zr2 (x=9–26) system was investigated using a series of cluster lines. Three types of clusters, an icosahedron (Fe12Y), a capped Archimedes anti-prism (Fe8B3) and a capped trigonal prism (Fe9B), as well as a binary eutectic (Fe83B17) were considered. Bulk glassy alloy rods of 3 mm in diameter were synthesized using a copper mold suction-casting method. The glass transition temperature was observed for all samples in the boron range of 15.9at%-25.7at%, with the alloy at 15.9at% of boron having the best thermal properties. The ferrous-based bulk metallic glasses (BMG) obtained have high reduced glass transition temperatures with the maximum reaching 0.63 and large supercooled liquid regions with the maximum reaching 111 K. Magnetic testing revealed a large value of coercive force and remanent magnetization, being 11 kA/m and 0.1 T, re- spectively.

【Abstract】 The glass forming ability of the [(Fe12/13Y1/13)100?xBx]96Nb2Zr2 (x=9–26) system was investigated using a series of cluster lines. Three types of clusters, an icosahedron (Fe12Y), a capped Archimedes anti-prism (Fe8B3) and a capped trigonal prism (Fe9B), as well as a binary eutectic (Fe83B17) were considered. Bulk glassy alloy rods of 3 mm in diameter were synthesized using a copper mold suction-casting method. The glass transition temperature was observed for all samples in the boron range of 15.9at%-25.7at%, with the alloy at 15.9at% of boron having the best thermal properties. The ferrous-based bulk metallic glasses (BMG) obtained have high reduced glass transition temperatures with the maximum reaching 0.63 and large supercooled liquid regions with the maximum reaching 111 K. Magnetic testing revealed a large value of coercive force and remanent magnetization, being 11 kA/m and 0.1 T, re- spectively.

【基金】 This project was financially supported by the National Natural Science Foundation of China (No.50401020, 50671018, 50631010);the Provincial Science and Technology Foundation of Liaoning, China.
  • 【文献出处】 Journal of University of Science and Technology Beijing ,北京科技大学学报(英文版) , 编辑部邮箱 ,2007年S1期
  • 【分类号】TG139.8
  • 【被引频次】2
  • 【下载频次】40
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