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Effect of Irradiation Grafting Epoxy on Surface Characteristics of Carbon Fibers and Mechanical Properties of Composites

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【作者】 徐志伟黄玉东闵春英陈盛洪

【Author】 Xu Zhiwei , Huang Yudong , Min Chunying , Chen Shenghong (Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China)

【机构】 Department of Applied Chemistry Harbin Institute of TechnologyDepartment of Applied Chemistry Harbin Institute of TechnologyHarbin 150001 China

【摘要】 Co60 γ-ray irradiation as a novel method for modification of fiber surface was introduced in the present study. Carbon fibers with kidney-type section were treated in a solution of epoxy resin and acetone using γ-ray irradiation. The effect of irradiation grafting epoxy on characteristics of carbon fibers was analyzed by using atomic microscopy (AFM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and impregnation performance testing. It is reveals that the fiber surface is roughened, the O/C ratio and C-O-C percentage increase rapidly and the wetting ability of fibers also improves after irradiation grafting. In addition, irradiation grafting is found to improve the adhesion at fiber/matrix interface and enhance the flexural and tensile strength of carbon fiber/phenolic composites with increasing the strength and modulus of fibers.

【Abstract】 Co60 γ-ray irradiation as a novel method for modification of fiber surface was introduced in the present study. Carbon fibers with kidney-type section were treated in a solution of epoxy resin and acetone using γ-ray irradiation. The effect of irradiation grafting epoxy on characteristics of carbon fibers was analyzed by using atomic microscopy (AFM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and impregnation performance testing. It is reveals that the fiber surface is roughened, the O/C ratio and C-O-C percentage increase rapidly and the wetting ability of fibers also improves after irradiation grafting. In addition, irradiation grafting is found to improve the adhesion at fiber/matrix interface and enhance the flexural and tensile strength of carbon fiber/phenolic composites with increasing the strength and modulus of fibers.

【基金】 Project supported by the National Natural Science Foundation of China (50333050)
  • 【文献出处】 Journal of Rare Earths ,稀土学报(英文版) , 编辑部邮箱 ,2006年S2期
  • 【分类号】TQ342.742
  • 【被引频次】3
  • 【下载频次】53
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