【摘要】 在有机合成中烯醇醚的水解是很普遍的,能观察到这类化合物的E/Z异构化是很少见的.我们发现并揭示了樟脑型β-烷氧基-β-不饱和酮的E/Z异构化的现象和过程,这一研究不仅提供了制备α、β不饱和烯醇醚的方法,而且对药物化学研究也有重要意义.更多还原

【Abstract】 We have disclosed an interesting E/Z isomerization process for camphor-derived β-alkoxy-β-unsaturated ketone.Hydrolysis of enol ether are common knowledge of organic synthesis,however,observation of E/Z isomerization rather than hydrolysis is rare.The result of this research is not so much as providing a method for the preparation of α,β-unsaturated enol ether,but as a valuable observation of an interesting phenomina that might find implication in pharmaceuticl chemistry.更多还原