【摘要】 利用Mn2+,Ba2+作为模板离子,由邻苯二胺和α,ω-二(3’-羟基-4’-甲酰苯氧基)取代烷[即1,4-二(3’-羟基-4’-甲酰苯氧基)丁烷、1,6-二(3’-羟基-4’-甲酰苯氧基)已烷、1,8-二(3’-羟基-4’-甲酰苯氧基)辛烷]反应分别合成了系列新型大环席夫碱化合物Ln(n=4,6,8)．Mn2+用于L4合成,并在洗涤时自动解络;L6和L8的合成以Ba2+模板,L6和L8的Ba2+配合物经与Na2SO4水溶液反应解络,得到自由大环配体L6和L8．上述新型大环席夫碱化合物采用元素分析,1H NMR,IR,紫外-可见光谱和MS等进行组成和结构表征．更多还原

【Abstract】 o-Phenylenediamine reacted with a series ofα,ω-bis(3’-hydroxy-4’-formylphenyloxy)alkanes to yield new macrocyclic Schiff base compounds (Ln), using Mn2+ or Ba2+as a template. The complex compounds have been solved by Na2SO4 solution and become free ligands. The structures of new macrocyclic compounds were characterized by elemental analysis, UV-vis spectrophotometry, 1H NMR, IR and MS spectra.更多还原