【摘要】 测定了298.15KKBph4在(CH3OH-H2O)混合溶剂中的溶解度,并根据热力学原理求算了KBph4在此混合溶剂中的饱和摩尔活度系数,离子缔合度和缔合常数,及KBph4由水(H2O)至混合溶剂(CH3OH-H2O)的标准迁移Gibbs自由能,并对KBph4的热力学性质随混合溶剂组成(x)的变化进行了初步的讨论.更多还原

【Abstract】 In this paper,the solubilities of KBph₄ in diferent compositions （CH₃OH-H₂O） mixtures at 298.15 K were determined by photometric method,and the activity coefficients,associate degrees,solubility products of ions of KBph₄ in (CH₃OH-H₂O mixtures and standard Gibbs free energies of transfer of KBph₄ from the pure water to ten compositions （CH₃OH-H₂O） mixtures at above experimental temperatures were obtained by thermodynamical principle.The changes of above thermodynamical properties of KBph₄ with organic composition （x） in （CH₃OH-H₂O） mixtures were discussed from theory of association and solvation of ions in solution.更多还原