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辽东楤木芽的化学成分(III)

Chemical constituents of the buds of Aralia elata(Miq.) Seem.(Ш)

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【作者】 李丽宋少江李玲芝梁振兴徐绥绪

【Author】 LI Li,SONG Shao-jiang,LI Ling-zhi,LIANG Zhen-xing,XU Suixu (School of Traditional Chinese Materia Medica,Shenyang Pharmaceutical University,Shenyang 110016,China)

【机构】 沈阳药科大学中药学院沈阳药科大学中药学院 辽宁沈阳110016辽宁沈阳110016

【摘要】 目的分离、鉴定辽东木(Aralia elata(Miq.)Seem.)芽提取物(总皂苷)中的化学成分。方法利用硅胶柱色谱,制备高效液相柱色谱进行分离纯化,根据理化性质和光谱数据进行结构鉴定。结果得到5个化合物,分别鉴定为Elatoside F(1)、Araloside G(2)、CongmunosideⅤ(3)、Congmuno-sideⅨ(4)、3O[βDglucopyranosyl(1→2)][βDglucopyranosyl(1→3)]αLarabinopyranosylhederagenin(5)。结论化合物5为一新天然产物。

【Abstract】 Objective To study the chemical constituents of the extract(crude saponins) of the buds of Aralia elata(Miq.) Seem.Methods Chemical constituents were isolated by silica gel column chromatography and preparative HPLC.Physical-chemical characters and the spectroscopic analysis were employed for the structural identification.Results Compound 1~5 were obtained and their structures were elucidated as elatoside F(1),araloside G(2),congmunoside V(3),congmunoside IX(4),3-O-[β-D-glucopyranosyl-(1→2)]-[β-D-glucopyranosyl-(1→3)]-α-L-arabinopyranosyl hederagenin(5).Conclusion Compound 5 is a new natural product.

【基金】 辽宁省博士启动基金项目(20031037)
  • 【文献出处】 沈阳药科大学学报 ,Journal of Shenyang Pharmaceutical University , 编辑部邮箱 ,2006年08期
  • 【分类号】R284.1
  • 【被引频次】18
  • 【下载频次】312
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