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辽东楤木芽的化学成分(III)
Chemical constituents of the buds of Aralia elata(Miq.) Seem.(Ш)
【摘要】 目的分离、鉴定辽东木(Aralia elata(Miq.)Seem.)芽提取物(总皂苷)中的化学成分。方法利用硅胶柱色谱,制备高效液相柱色谱进行分离纯化,根据理化性质和光谱数据进行结构鉴定。结果得到5个化合物,分别鉴定为Elatoside F(1)、Araloside G(2)、CongmunosideⅤ(3)、Congmuno-sideⅨ(4)、3O[βDglucopyranosyl(1→2)][βDglucopyranosyl(1→3)]αLarabinopyranosylhederagenin(5)。结论化合物5为一新天然产物。
【Abstract】 Objective To study the chemical constituents of the extract(crude saponins) of the buds of Aralia elata(Miq.) Seem.Methods Chemical constituents were isolated by silica gel column chromatography and preparative HPLC.Physical-chemical characters and the spectroscopic analysis were employed for the structural identification.Results Compound 1~5 were obtained and their structures were elucidated as elatoside F(1),araloside G(2),congmunoside V(3),congmunoside IX(4),3-O-[β-D-glucopyranosyl-(1→2)]-[β-D-glucopyranosyl-(1→3)]-α-L-arabinopyranosyl hederagenin(5).Conclusion Compound 5 is a new natural product.
【Key words】 medicinal chemistry; structural identification; NMR; Aralia elata; triterpenoidal saponin;
- 【文献出处】 沈阳药科大学学报 ,Journal of Shenyang Pharmaceutical University , 编辑部邮箱 ,2006年08期
- 【分类号】R284.1
- 【被引频次】18
- 【下载频次】312