【摘要】 以取代苯乙酮为原料,首次得到了反应中间体二-(1,1-二氯-1-芳酰基)三硫醚,对其进行了红外、核磁、质谱和X-衍射分析,并且用该化合物与仲胺反应得到了六个α-羰基硫代甲酰取代胺。更多还原

【Abstract】 Acetophenone and its derivatives reacted with thionyl chloride to afford bis (1, 1-dichloro-1-aroyl) trisulfides, followed by reacting with the secondary amines to giveα-carbonyl-N, N-disubstitued thioformamides. The structures of all compounds were confirmed by IR、NMR、MS spectra, furthermore, the structure of bis (1,1-dichloro-1-benzoyl) trisulfide was analyzed by X-ray diffraction method.更多还原