【摘要】 合成了一个金鸡纳霜生物碱衍生的季铵盐,并通过元素分析、红外、核磁和X-射线衍射进行了结构表征.空间群为P 2(1)2(1)2,晶胞参数a=1.050 2(1)nm,b=2.819(3)nm,c=0.879 5(8)nm,V=2.6040(4)nm3,Z=4.该化合物在π-π堆积和氢键等超分子导向作用下组装成新颖的有机双链螺旋和三维氢键超分子结构.更多还原

【Abstract】 The title compound was synthesized and characterized by means of single crystal X-ray diffraction,elemental analysis,FT-IR,~1H NMR.The complex crystallized in a orthorhombic system with space group P2(1)2(1)2 and crystal cell parameters a= 1.050 2(1) nm,b= 2.819(3) nm,c= 0.879 5(8) nm,β=90,V=2.604 0(4) nm~3,Z=4.The title compound possesses novel hydrogen-bonded three-dimensional(3-D) network,in which unusual 1-D hydrogen-bonded organic double-stranded helical chains assembled from wrapping of two single-stranded helical chains around each other via aromatic π-π stacking interactions.更多还原