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微米棒构筑的多脚状ZnO水热合成及生长机理探讨

Synthesis of uniform multipod-like ZnO microcrystals and their growth mechanism under hydrothermal condition

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【作者】 曲江英王旭珍邹龙江

【Author】 Qu Jingying~1 Wang Xuzhen~1 Zou Longjiang~2(1.School of Chemical Egineering,Dalian University of Technology,Dalian 116023;2.School of Material Science,Dalian University of Technology,Dalian 116023)

【机构】 大连理工大学化工学院大连理工大学材料学院 大连116023大连116023

【摘要】 以Zn(CH3COO)2和NH3.H2O生成的Zn(NH3)42+为前驱体,采用水热法制备了多脚状ZnO微晶,用XRD、SEM、TEM及UV-Vis进行了鉴定和表征,并对其生长机理进行了初步探讨。结果表明,多脚状ZnO微晶由微米棒构筑,属六方晶系,在短紫外光区具有较强的光吸收性能。

【Abstract】 Multipod-like zinc oxide microcrystals were synthesized by a simple hydrothermal process by decomposing Zn(NH32+4 precursor.The obtained ZnO was characterized by XRD,SEM.,TEM and UV-Vis.Results showed that the Multipod-like ZnO microcrystals had pure hexagonal structure with several rod-like legs united at a common junction and showed strong short UV spectra absorption.The possible formation mechanisms of ZnO powders during the hydrothermal processing were also proposed.

【关键词】 氧化锌水热合成多脚状机理
【Key words】 zinc oxidehydrothermal treatmentmultipod-likegrowth mechanism
【基金】 国家自然科学基金项目(20276012);大连理工大学青年教师培养基金项目
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2006年01期
  • 【分类号】O614.241
  • 【被引频次】5
  • 【下载频次】308
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