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含1,3,4-噁二唑甲壳型液晶聚合物的合成与表征

SYNTHESIS AND CHARACTERIZATION OF MESOGEN-JACKETED LIQUID CRYSTALLINE POLYMER CONTAINING 1,3,4-OXADIAZOLE

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【作者】 柴春鹏王婧范星河陈小芳周其凤

【Author】 CHAI Chunpeng, WANG Jing, FAN Xinghe, CHEN Xiaofang, ZHOU Qifeng(Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education College of Chemistry and Molecular Engineering, Peking University, Beijing 100871)

【机构】 北京大学化学与分子工程学院北京分子科学国家实验室教育部高分子化学与物理重点实验室北京大学化学与分子工程学院北京分子科学国家实验室教育部高分子化学与物理重点实验室 北京100871北京100871

【Abstract】 A series of monomers {2,5-bis[(5-alkyl-phenyl)-1,3,4-oxadiazole] styrene}(BOXE) were designed and synthesized.By radical polymerization initiated BPO with a novel series of mesogen-jacketed polymers containing 1,3,4-oxadiazole were prepared.Molecular weight and molecular weight distribution of polymers were measured by GPC.The glass transition temperature (T_g) and thermal stability of polymers were studied by DSC and TGA.The results indicate that these polymers have good thermal stability.These liquid crystal polymers have well defined structure,and possess special photo-electronic properties.

【基金】 国家自然科学基金(基金号20134010,20574002);教育部科学技术重点基金(基金号104005);教育部博士后基金(基金号2004036168)资助项目
  • 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2006年03期
  • 【分类号】O631.3
  • 【被引频次】10
  • 【下载频次】286
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