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无氟预熔LF精炼渣的开发与应用研究

Development and Application of LF Refining Pre-Melted Slag Without CaF2

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【作者】 潘贻芳; 凌遵峰; 王宝明; 李树庆; 王振峰;

【Author】 PAN Yi-fang~1,LING Zun-feng~1,WANG Bao-ming~1,LI Shu-qing~1,WANG Zhen-feng~2(1.Tianjin Iron and Steel Co.,Ltd.,Tianjin 300301,China;2.Department of Material Science and Engineering,Zhengzhou 450052,Henan,China)

【机构】 天津钢铁股份有限公司; 郑州大学材料科学与工程学院 天津300301; 天津300301; 河南郑州450052;

【摘要】 为了避免有氟渣的氟污染问题,结合炉渣基础理论,设计开发出了CaO-Al2O3-MgO-SiO2系无氟精炼渣。精炼渣的工业应用表明,该渣能满足BOF-LF-CC工艺生产石油套管钢(37Mn5、34Mn5)的要求,钢管的实物质量达到美国石油行业API.5CT标准,并可使LF精炼操作时间由42 min缩短到35 min,为高效生产和快节奏奠定了基础。与常规有氟渣相比,避免了氟污染问题,且达到了脱氧、脱硫效果好,精炼初期成渣快、发泡埋弧效果好及包衬侵蚀较轻的目的。

【Abstract】 In order to avoid the fluorine pollution,the LF refining pre-melted CaO-Al2O3-MgO-SiO2 slag without CaF2 was developed based on the molten slag theory.The industrial practice showed that the slag was suitable for the BOF-LF-CC route to produce oil-well pipe steel such as 37Mn5 and 34Mn5,etc,according to the standard of API.5CT of USA,and the operation period of LF refining was decreased from 42 min to 35 min,establishing the foundation of high efficiency production and short production cycle.Meanwhile the slag,compared with the slag with CaF2,has good properties for desulphurization,deoxidation,and arc submerging,quick slag forming at the beginning of refining and foaming,as well as the advantages of lower lining erosion and no pollution of fluorine.

【关键词】 LF; 无氟精炼渣; 脱硫;
【Key words】 ladle furnace; refining slag without CaF2; desulphurization;
  • 【文献出处】 钢铁 ,Iron & Steel , 编辑部邮箱 ,2006年10期
  • 【分类号】TF769
  • 【被引频次】12
  • 【下载频次】381
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