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3种重金属离子对海水中亚硝化、硝化作用的影响

Effects of three heavy metal ions on nitrosification and nitrification in sea water

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【作者】 翁永根邢永张长新王斌雷衍之

【Author】 WENG Yong-gen~(1,2), XING Yong~(3), ZHANG Chang-xin~(3), WANG Bin~(2), LEI Yan-zhi~(2)(1.Department of Applied Chemistry,Yantai University,Yantai 264005,China;2.School of Life Science and Technology, Dalian Fisheries Univ.,Dalian 116023,China;3.Panjing Guanghe Aquatic Product Ltd.,Panjing 124200,China)

【机构】 烟台大学应用化学系盘锦光合水产有限公司大连水产学院生命科学与技术学院大连水产学院生命科学与技术学院 山东烟台264005辽宁大连116023辽宁盘锦124200

【摘要】 研究了Cu2+、Cd2+、Zn2+3种重金属离子对海水中亚硝化、硝化作用的影响。重金属离子对亚硝化作用影响的试验结果表明:当水体中Cu2+、Cd2+的浓度为0.1、0.5、1.0 mg/L以及Zn2+的浓度为0.5、1.0、5.0 mg/L时,NO2--N浓度的增加量与对照组相比明显缓慢,随着3种重金属离子浓度的增加,此现象不断加强;重金属离子对亚硝化作用抑制程度的顺序为Cu2+>Cd2+>Zn2+,这与3种金属硫化物的稳定性是一致的。重金属离子对硝化作用影响的试验结果表明:低浓度试验组中NO2--N浓度的减少量与对照组比没有显著性差异,当Cu2+、Cd2+浓度增为5.0 mg/L时,对硝化作用产生明显的抑制;而同浓度的Zn2+对硝化作用却没有抑制;3种重金属离子对硝化作用抑制程度的顺序为Cu2+>Cd2+>Zn2+。试验还发现,Cu2+对硝化作用产生抑制后,其硝化功能很难得到恢复。

【Abstract】 The effects of heavy metal ions Cu2+,Cd2+,and Zn2+ on nitrosification and nitrification in sea water were studied by changes in concentration of NO-2-N from ammonia-oxidizing bacteria.It was found that concentration of NO-2-N significantly slowly increased at 0.1,0.5 and 1.0 mg/L Cu2+and Cd2+ and 0.5,(1.0) and 5.0 mg/L Zn2+compared with control group.The order of nitrosification inhibition from highest to lowest arranged as Cu2+>Cd2+>Zn2+,which is consistent with stability of sulfates.There was no significant difference in decrease in concentration of NO-2-N at low concentrations of Cu2+,Cd2+ and Zn2+ compared with control group.However,significant inhibition occurred when the concentration of Cu2+and Cd2+was 5.0 mg/L.There was no effect of Zn2+ on nitrosification and nitrification.The order of nitrification inhibition from highest to lowest was arranged as Cu2+>Cd2+>Zn2+.

【关键词】 硝化作用重金属离子NO2--N抑制
【Key words】 nitrificationheavy metalNO-2-Ninhibition
【基金】 欧盟第五框架计划项目ZAFIRA资助(ICA4-CT-2001-10025);辽宁省教育厅高校科研项目资助(20102135)
  • 【文献出处】 大连水产学院学报 ,Journal of Dalian Fisheries University , 编辑部邮箱 ,2006年01期
  • 【分类号】X55
  • 【被引频次】5
  • 【下载频次】296
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