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LiNi1/3Co1/3Mn1/3O2正极材料的413450型电池的性能

The performance of 413450 type battery with LiNi1/3Co1/3Mn1/3O2 as cathode material

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【作者】 胡国荣谭显艳高旭光彭忠东

【Author】 HU Guo-rong,TAN Xian-yan,GAO Xu-guang,PENG Zhong-dong(College of Metallurgy Science and Engineering,Central South University,Changsha,Hunan 410083,China)

【机构】 中南大学冶金科学与工程学院中南大学冶金科学与工程学院 湖南长沙410083湖南长沙410083

【摘要】 采用自制的LiNi1/3Co1/3Mn1/3O2作正极材料,以石墨作负极,组装成413450型锂离子电池。分别在25℃和55℃下以3.0~4.2 V为电压区间,1C充放电,对其电化学性能进行测试和研究。结果表明:55℃下电池的首次放电比容量为143 mAh/g,25℃下为138 mAh/g;电池在55℃下充放电循环85次,容量保持率为92.15%。过充、热冲击和常温短路实验的顺利通过,证明样品材料有很好的安全性能。

【Abstract】 The 413450 type battery had been made by using graphite as anode material and self-made LiNi1/3Co1/3Mn1/3O2 as cathode material.The electrochemical performance was studied and tested at 25 ℃ and 55 ℃,charged-discharged between 3.0~4.2 V with 1 C rate.The results showed that the initial discharge specific capacity of the battery was 143 mAh/g at 55 ℃ and 138 mAh/g at 25 ℃.The capacity retention rate of the battery was 92.15% after 85 charge-discharge cycles at(55 ℃.)The overcharging,thermal shock and the normal temperature short circuit tests of the batteries had been passed.The results proved that the sample material had good safety performance.

  • 【文献出处】 电池 ,Battery Bimonthly , 编辑部邮箱 ,2006年02期
  • 【分类号】TM912.9
  • 【被引频次】4
  • 【下载频次】237
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