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球形木素基离子交换树脂的合成及基本性能

Preparation and Fundamental Characteristics of Spherical Lignin-Based Ion Exchange Resin

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【作者】 范娟; 詹怀宇; 尹覃伟; 刘明华;

【Author】 FAN Juan~1,* ZHAN Huai-yu1 YIN Qin-wei1 LIU Ming-hua2(1.State Key Lab of Pulp &Paper Engineering,South China University of Technology,Guangzhou, Guangdong Province, 510640;2.Dept. of Environment and Resources Engineering, Fuzhou University, Fuzhou, Fujian Province,350002)

【机构】 华南理工大学制浆造纸工程国家重点实验室; 福州大学 广州; 510640; 广州; 福州; 350002;

【摘要】 以木素磺酸钙为原料,利用反相悬浮聚合技术制备出球状木素基离子交换树脂。研究了分散相、分散剂、聚合温度、搅拌条件及交联剂用量等对悬浮聚合反应及成球效果的影响,并对产品的外观、粒度、含水量、密度及交换容量等基本性能进行了表征和测定。在优化条件下制得的球形木素基离子交换树脂的交换容量可达3.83mmol/g。

【Abstract】 A spherical lignin-based ion exchange resin was prepared with calciumlignosulfonate as raw material in a cheap and non-toxic disperse phase by reversed phase suspension polymerization technique. The effect of disperse phase, dispersing agent and cross-linking agent dosage, polymerization temperature and mixing speed on the suspension polymerization and sphericization were studied in detail. The fundamental performances of the resin including appearance, particle size, moisture content, density, and exchange capacity were characterized. At the optimal conditions, the ion exchange capacity of 3.83 mmol/L was reached.

  • 【文献出处】 中国造纸 ,China Pulp & Paper , 编辑部邮箱 ,2005年05期
  • 【分类号】TQ425.23
  • 【被引频次】5
  • 【下载频次】221
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