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农膜光转换添加剂的XPS剖析

XPS Dissection of the Optical Transition Additive in Farm Film

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【作者】 孙海珍王水菊陈谋智陈松岩蔡加法

【Author】 SUN Hai-zhen 1,3,WANG Shui-ju 2,3,CHEN Mou-zhi 4,CHEN Song-yan 4,CAI Jia-fa 4(1.Department of Chemistry,Xiamen University,Xiamen361005,China;2.State Key Laboratory for Physics Chemistry of Solid Surface,Xiamen University,Xiamen361005,China;3.Analysis and Testing Centre,Xiamen University, Xiamen361005,China;4.Department of Physics,Xiamen University,Xiamen361005,China)

【机构】 厦门大学化学系厦门大学固体表面物理化学国家重点实验室厦门大学物理系厦门大学物理系 福建厦门361005厦门大学分析测试中心福建厦门361005

【摘要】 报道了无保护气氛条件下,采用高温固相还原法合成适用于农用塑料地膜的光转换添加剂,共掺铜、铕激活剂的硫化钙(CaS)无机荧光材料,用X射线光电子能谱(XPS)方法对光转换添加剂中不同工艺下激活剂元素进行表征,再通过光致发光谱、透射光谱测量,探索材料中激活剂的能量传输特性,为高新农业的发展提供清洁能源。

【Abstract】 An optical transition additive used in farmfilmwas synthesized by doping the Cu and Eu activators into an inorganic fluorescent material,CaS with the high-temperature solid phase reduction method under unˉprotected atmosphere.The characteristics of the activators in the films prepared under different conditions were measured by X-ray photo-electron spectroscopy.The energy-transfer properties of the activators in the films were investigated by the photo-induced luminescence spectra and transmission spectra.It is useful for developing a clean energy source in agriculture.

【关键词】 硫化钙光转换添加剂激活剂
【Key words】 CaSOptical transition additiveActivator
【基金】 福建省自然科学基金资助项目(A0110006);厦门大学自选课题基金资助项目(Y07007)
  • 【文献出处】 分析测试学报 ,Journal of Instrumental Analysis , 编辑部邮箱 ,2005年06期
  • 【分类号】TQ320.4
  • 【被引频次】2
  • 【下载频次】117
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