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硅烷接枝交联HDPE铝塑复合管专用料的研究

The Crosslinking of Silane Grafted HDPE for PE-Al-PE Pipe

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【作者】 段景宽王秀丽张广明李静

【Author】 DUAN Jing-kuan~(1,2),WANG Xiu-li~2,ZHANG Guang-ming~2,LI Jing~2(1.Research Center of Material Science and Engineering of Guilin Electronic and Engineering University,Guilin,Guangxi 541004,China;2.Resin Research Institute of Qilu Petrochemical Corp,Linzi,Shandong 255400,China)

【机构】 桂林电子工业学院材料中心齐鲁石化公司树脂研究所齐鲁石化公司树脂研究所 广西桂林 541004齐鲁石化公司树脂研究所山东临淄 255400临淄 255400

【摘要】 以双螺杆挤出机为反应器,考察了影响聚乙烯接枝交联的主要因素,如基础树脂的配比,引发 剂、交联剂的用量及种类,催化剂的用量。通过对这些因素的详细研究,得出了硅烷交联高密度聚乙烯 铝塑复合管专用料的最佳配方。接枝料(质量份数):5000S为55份,7006A为20份,载体树脂为25份, 复配交联剂Ⅰ为2份,抗氧剂2为0 1份,阻聚剂Ⅰ为0 12份,阻聚剂Ⅱ为0 04份。催化料(质量份 数):5000S为85份,载体树脂为15份,催化剂为1份,抗氧剂Ⅰ为0 3份,抗氧剂Ⅱ为0 3份。交联料 (质量份数):接枝料95份,催化料5份。

【Abstract】 The grafting of vinyl silane onto HDPE and crosslinking of silane grafted HDPE were studied by the twin screw extruder.Through the elaborate study of the main factors of the grafting of vinyl silane outo HDPE and crosslinking of silane grafted HDPE,such as the constituent of resins,the content and kinds of initiating agents,crosslinking agents adn inhibitor,the content of catalyst,an optimum formulation was obtained about corsslinking of silane crafted HDPE for PE-Al-PE pipe.The corsstituent of grafted material(part by weight):5000S is 55,7006A is 20,support resin is 25,compound crosslinking agent Ⅰis 2,antioxidant 2 is 0.1,inhibitor Ⅰis 0.12,inhibitor Ⅱ is 0.04.The constituent of catalyst material(part by weight):5000S is 85,support resin is 15,catalyst is 1,antioxidant 1 is 0.3,antioxidant 2 is 0.3.The constituent of crosslinking material(part by weight):grafted material is 95,catalyst material is 5.

【关键词】 乙烯基硅烷高密度聚乙烯接枝交联铝塑复合管
【Key words】 vinyl silaneHDPEgraftingcrosslinkingPE-Al-PE pipe
  • 【文献出处】 塑料 ,Plastics , 编辑部邮箱 ,2005年01期
  • 【分类号】TQ325.12
  • 【被引频次】6
  • 【下载频次】163
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