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氧化剂对CWAO降解垃圾渗滤液中有机物的影响

Effect of Oxidant on the Decomposition of Organic Compounds in the Landfill Leachate by CWAO

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【作者】 刘亮李鱼刘光辉王健董德明李海生

【Author】 LIU Liang~1, LI Yu~1, LIU Guang-hui~1, WANG Jian~1, DONG De-ming~1, LI Hai-sheng~2(1. College of Environment and Resources, Jilin University, Changchun 130012, China; 2. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

【机构】 吉林大学环境与资源学院北京化工大学化学化工学院 长春130012长春130012北京100029

【摘要】 将催化湿式氧化技术应用于垃圾渗滤液中有机物的降解,着重研究了氧化剂(以氧分压表征)对降解效果的影响.结果表明:氧化剂是影响垃圾渗滤液中有机物降解反应的重要因素之一,随着氧分压的增大,催化氧化反应速率逐渐增加,其降解过程符合Allometric方程(Y=aXb),但随着氧分压的增大,催化氧化反应速率增加的幅度逐渐减小,并分析了其原因.

【Abstract】 Catalytic wet air oxidation(CWAO) was employed to reduce the organic compounds in the landfill leachate and the influence of oxidant (characterized by oxygen partial pressure) on the degradation was investigated. The results indicate that the oxidant is an important factor in treating leachate by CWAO and decomposition rate of the organic (pollutants) increases with the rise of oxygen partial pressure, but the influence of (oxidant) on the decomposition rate decreases gradually with the increase of oxygen partial pressure. The dynamics course of the organic (compounds) degradation could be described with the Allometric equation(Y=aX~b), and the mechanisms (analyses) were given.

【基金】 国家环保总局环境工程评估中心项目基金(批准号:02220100000549);吉林省环境保护项目基金(批准号:2003007).
  • 【文献出处】 吉林大学学报(理学版) ,Journal of Jilin University (Science Edition) , 编辑部邮箱 ,2005年04期
  • 【分类号】X703
  • 【被引频次】19
  • 【下载频次】198
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