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含磺酸基单体在炭黑表面接枝共聚合

GRAFTING CONTAINING SULFONIC ACID GROUP ONTO CARBON BLACK SURFACE COPOLYMERIZATION OF MONMERS

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【作者】 赵建义王成扬李同起

【Author】 ZHAO Jianyi~(1,2), WANG Chengyang~1, LI Tongqi~1(()~1Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin\ 300072)(()~2North University of China, Taiyuan\ 030008)

【机构】 天津大学化工学院绿色合成与转化教育部重点实验室天津大学化工学院绿色合成与转化教育部重点实验室 天津300072中北大学分校太原030008天津300072天津300072

【Abstract】 To increase the dispersion stability of carbon black in water,polymers with sulfonic acid groups were grafted onto the surface of carbon black.Under the effect of ultrasonic wave,sodium allyl sulfonate (SAS) and 2-acrylamido-2-methyl propane sulfonic acid (AMPS) were copolymerized with acrylic acid and grafted onto the surface of carbon black, respectively by means of redox of ceric ion and nitric acid.The copolymerization conditions and dispersion stability of grafted carbon black were discussed in detail.It was found that the introduction of sulfonic acid groups improved the dispersion stability of carbon black in water obviously.It was also noticed that AMPS was easier to copolymerize with acrylic acid compared with SAS. For obtaining the highest grafting percentage,SAS and AMPS both had an optimal quantity when the weight of acrylic acid was constant and the ratios of them to acrylic acid (in weight) were within 0.15~1.0.

  • 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2005年04期
  • 【分类号】TQ316.6
  • 【被引频次】3
  • 【下载频次】234
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