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海泡石负载Cu催化糠醛气相加氢制糠醇反应

Sepiolite-supported Cu Catalyst for Vapour Phase Hydrogenation of Furfural to Furfuryl Alcohol

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【作者】 乐治平黄艳秋代丽丽

【Author】 LE Zhi-ping~1, HUANG Yan-qiu~2, DAI Li-li~1 (1. Department of Chemistry, Nanchang University, Nanchang 330047, China; 2. Graduate school, Nanchang University, Nanchang 330047, China)

【机构】 南昌大学化学系南昌大学研究生院南昌大学化学系 江西南昌330047江西南昌330047江西南昌330047

【Abstract】 A kind of sepiolite-supported copper-based catalyst by impregnation method using Cu(NO32 aqueous solution is prepared. In this paper, the activity of Cu/Sep for hydrogenation of furfural to furfuryl alcohol at atmospheric pressure has been studied in a pulse type reactor. The effects of Cu content, reaction temperature, inject amount were examined. The catalysts was characterized by TPR. The result revealed that Cu/Sep demonstrated good catalytic performance. Under the experimental conditions (135 ℃, Cu loading 18.1% and normal pressure ), the conversion of furfural and selectivity of furfuryl alcohol are all 100%. The result of TPR indicated that Cu dispersion decreased with the increase of Cu load.

【关键词】 海泡石糠醛糠醇加氢
【Key words】 SepioliteCopperFurfuralFurfuryl alcoholHydrogenation
  • 【文献出处】 分子催化 ,Journal of Molecular Catalysis , 编辑部邮箱 ,2005年01期
  • 【分类号】TQ25
  • 【被引频次】17
  • 【下载频次】233
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