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多层电解质型中温SOFC

Intermediate temperature SOFC with multi-layer electrolyte

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【作者】 毕忠合衣宝廉程谟杰

【Author】 BI Zhong-he, YI Bao-lian, CHENG Mo-jie(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China)

【机构】 中国科学院大连化学物理研究所中国科学院大连化学物理研究所 辽宁大连 116023辽宁大连 116023辽宁大连 116023

【摘要】 采用柠檬酸法合成了Gd0 1Ce0 9O1 95(GDC)、La0 45Ce0 55O2-σ/2(LDC)、La0 9Sr0 1Ga0 8Mg0 2O2 85(LSGM)电解质材料,并制备了阳极负载型GDC LSGM、LDC LSGM和LDC LSGM LDC多层薄膜电解质单体电池,考察了单体电池的U J特性和功率输出性能。结果显示:GDC LSGM电解质电池没有电流产生;LDC LSGM电解质电池最大输出功率密度最高,800℃时约为0 72W/cm2,但不稳定;LDC LSGM LDC多层电解质电池的开路电压最高,800℃时可达0 814V。

【Abstract】 Gd0.1Ce0.9O1.95(GDC), La0.45Ce0.55O2-σ/2(LDC) and La0.9Sr0.1Ga0.8Mg0.2O2.85(LSGM) electrolyte materials were synthesized by the citric method. Anode-supported single cells with GDC-LSGM, LDC-LSGM and LDC-LSGM-LDC multi-layer thin film electrolyte were prepared. The U-J characteristics and output power performance of the single cells were measured. The results showed that no current could be taken from the cell with GDC-LSGM electrolyte.The cell with LDC-LSGM electrolyte gave the maximum output power density of 0.72 W/cm2 at 800 ℃, but it was not stable. The open circuit voltage of the cell with LDC-LSGM-LDC electrolyte was the highest, reaching to 0.814 V at 800 ℃.

【基金】 中国科学院知识创新工程领域前沿项目(K200D13)
  • 【文献出处】 电池 ,Battery Bimonthly , 编辑部邮箱 ,2005年01期
  • 【分类号】TM911.4
  • 【被引频次】7
  • 【下载频次】206
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