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具有高活性及扩孔结构载体的Mo-Co/r-Al2O3催化剂的制备方法及其性能优化

PREPARATION AND FINE PERFORMANCE OF Mo-Co/r-Al2O3 CATALYST WITH THE CARRIER OF HIGH ACTIVITY AND REAMING STRUCTURE

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【作者】 秦玉楠

【Author】 QIN Yu-nan(Chengdu Huilong Chemical Plant,Chengdu 610306,Sichuan,China)

【机构】 成都慧龙化工总厂专家工作组 成都 610306

【摘要】 详实阐述了对国产加氢转化脱有机硫(HDS)Mo-Co/r-Al2O3催化剂载体r-Al2O3进行改进的结构机理。采用"并流中和法"制得了低钠、低表观密度的拟薄水铝石("假~水"晶相)原料,添加适当助剂,制备出高强度、低表观密度的r-Al2O3载体,大大提高了中孔的比率。使用新型载体制备的HDS催化剂,其有机硫转化活性达99%。

【Abstract】 The improvements of HDS catalyst carrier r-Al2O3 were detailed described in this paper.First,the raw material pseudo-boehmite with low sodium content and low bulk density can be prepared by neutralization,then the auxiliary agent is added,the r-Al2O3 carrier with high strength and low bulk density can be obtained.The carrier improved possesses large proportion of medium pore and the Mo-Co/r-Al2O3 HDS catalyst with such r-Al2O3 carrier has the activity of 99% for the convertion of organic sulfur.

【关键词】 拟薄水铝石r-Al2O3载体Mo-Co/r-Al2O3
【Key words】 pseudo-boehmiter-Al2O3carrierMo-Co/r-Al2O3 catalyst
  • 【文献出处】 中国钼业 ,China Molybdenum Industry , 编辑部邮箱 ,2004年01期
  • 【分类号】TQ426
  • 【被引频次】6
  • 【下载频次】270
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