【摘要】 合成了Y和Dy与β-丙氨酸的配合物,并测定了其晶体结构,配合物组成为{[Ln2(β-ala)6(H2O)4](ClO4)6·H2O}n(Ln=Y(1)、Dy(2)),配合物均属于三斜晶系,P1空间群,晶胞参数为:(1):a=1.2903(3)nm,b=2.1667(4)nm,c=0.92100(18)nm,α=98.73(3)°,β=97.02(3)°,γ=76.89(3)°,V=2.4683(3)nm3,Z=2,Dc=1.881mg·m-3;(2):a=0.9222(2)nm,b=1.2875(3)nm,c=2.1634(5)nm,α=77.01(2)°,β=81.21(2)°,γ=82.89(2)°,V=2.4629(10)nm3,Z=2,Dc=2.082mg·m-3,两个配合物具有类似的晶体结构,均为无限链状分子,Ln( )离子为九配位的单帽四方反棱柱配位多面体。更多还原

【Abstract】 Two rare earth complexes of β-alanine with the formula of ｛[Ln₂（β-ala）₆（H₂O）₄]（ClO₄）₆·H₂O｝_n（where Ln=Y（1）,Dy（2）） have been syntheses and characterized by IR,and X-ray diffraction analysis.Both of the compounds crystallize in triclinic system with space group P_（1）.Crystal data:（1）:a=1.2903（3）nm,b=2.1667（4）nm,c=0.92100（18）nm,α=98.73（3）°,β=97.02（3）°,γ=76.89（3）°,V=2.4683（3）nm³,Z=2,D_c=1.881mg·m^-3;（2）:a=0.9222（2）nm,b=1.2875（3）nm,c=2.1634（5）nm,α=77.01（2）°,β=81.21（2）°,γ=82.89（2）°,V=2.4629（10）nm³,Z=2,D_c=2.082mg·m^-3.The two complexes hae similar structures with one-dimensional infinite chains.Both of the rare earth ions are coordinated with seven oxygen atoms of β-alanine ligands and two oxygen atoms of two water molecules,forming distorted mono caped square antiprism.更多还原