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新型囊泡状二氧化硅中孔分子筛的合成与表征

SYNTHESIS AND CHARACTERIZATION OF A NOVEL MESOPOROUS VESICLE SILICA MOLECULAR SIEVE

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【作者】 朱金红刘靖赵文江王祥生

【Author】 ZHU Jin-hong, LIU Jing, ZHAO Wen-jiang, WANG Xiang-shengn 116012, China)

【机构】 大连理工大学精细化工国家重点实验室大连理工大学精细化工国家重点实验室 辽宁大连 116012辽宁大连 116012辽宁大连 116012

【Abstract】 Mesoporous silica molecular sieve (denoted MDL) has been prepared by the hydrolysis and condensation of tetraethylorthosilicate (TEOS) in the presence of industrial production N-dodecyl-1, 3-diaminopropane surfactant, which act as the structure-directing (templating) agent, through a supramolecular assemble mechanism between the gemini surfactant and Si(OC2H54-x(OH)x silica precursors. The mesoporous molecular sieve has vesicle-like particle texture and lamellar framework, as confirmed by Scanning electron microcopy (SEM) and Transmission electron microcopy (TEM). The most prior preparation condition is mentioned from the influence of preparation conditions to as-synthesized samples by X-ray power diffaration (XRD). FT-IR spectra show the existence of the mesoporous silica framework.

  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,2004年03期
  • 【分类号】O643.3
  • 【被引频次】3
  • 【下载频次】158
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