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甲醇、甲醛和甲酸在碳载纳米Pt电极上的催化氧化

Electrocatalytic Oxidation of Methanol, Formaldehyde and Formic Acid on the Nano-PT/GC Electrode

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【作者】 李小芳张亚利孙典亭焦奎

【Author】 LI Xiao-fang~1, ZHANG Ya-li~1, SUN Dian-ting~1, JIAO Kui~2(1. College of Chemical Engineering, Qingdao Univerity,Qingdao 266071, China; 2. Qingdao Univerity of Science &Technology, Qingdao 266043, China)

【机构】 青岛大学化工学院青岛科技大学 山东青岛266071山东青岛266071山东青岛266043

【摘要】 将纳米Pt/玻碳电极应用于甲醇、甲醛和甲酸的电催化氧化,发现所制备的催化剂电极具有较高的电催化活性。探讨了甲醇、甲醛和甲酸在纳米Pt/玻碳电极上的催化机理。

【Abstract】 The nano-Pt /GC electrode,which was prepared by electrochemical cyclic voltammetry, has been applied to the electrochemical oxidation of methanol, formaldehyde and formic acid. The results demonstrate that the electrode exhibits the high electro-catalytic activity, the mass current density of nano-Pt /GC electrode is ca 4-5 orders of magnitude as high as that of the Pt electrode. The origins of various peaks in relation to the oxidation of methanol, formaldehyde and formic acid are also explained.

  • 【文献出处】 青岛大学学报(工程技术版) ,Journal of Qingdao University Engineering & Technology Edition , 编辑部邮箱 ,2004年01期
  • 【分类号】O646.54
  • 【被引频次】18
  • 【下载频次】394
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