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松香酸聚氧乙烯酯磺基琥珀酸单酯二钠盐的合成及性能
Synthesis and Properties of Disodium Sulfosuccinate Monoester of Polyoxylethylene Abietate
【摘要】 考察了松香酸聚氧乙烯酯磺基琥珀酸单酯二钠盐的合成工艺条件,并测定了合成产物的表面化学性能。较佳的合成工艺条件为:松香酸聚氧乙烯酯与顺酐摩尔比为1:1.05,酯化温度95℃,酯化时间3.0 h;顺酐与亚硫酸钠摩尔比为1:1,磺化温度80℃,磺化时间3.5 h。性能测试和应用结果表明,该产物具有良好的乳化力和分散力,对大庆黑帝庙稠油具有较好的乳化降粘效果。
【Abstract】 The synthetic conditions and surface properties of disodium sulfosuccinate monoester of polyoxylethylene abietate(DSMPA) were investigated in the paper. The optimal process conditions for esterification were as follows: the molar ratio of polyoxylethylene to maleic anhydride 1:1.05, temperature 95 ℃, time 3.0 h.for sulfonation, the molar ratio of maleic anhydride to sodium sulfite 1:1, temperature 80 t, time 3 .5 h. The property tests and application results showed that DSMPA had excellent dispersibility, emulsifying ability and high viscosity reducing efficiency for emulsifying Daqing Heidimiao heavy crude oils.
【Key words】 polyoxylethylene abietate; disodium sulfosuccinate monoester; esterification; sulfonation; viscosity reduction by emulsification;
- 【文献出处】 精细石油化工进展 ,Advances in Fine Fetrochemicals , 编辑部邮箱 ,2004年04期
- 【分类号】TQ423
- 【被引频次】14
- 【下载频次】190