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多孔金属连续电沉积数学模型
MATHEMATICAL MODEL OF CONTINUOUS ELECTRODEPOSITION OF POROUS METAL
【摘要】 采用电沉积方法制备连续多孔金属 ,通过把电流密度随时间的变化转换为镀区内的位置分布 ,建立了稳恒状态下高孔率带状多孔金属连续电沉积动态模型 ,推导出表观电流密度分布的数学表达式 .并在多孔金属镍实际制备过程中对模型进行了验证 ,结果表明带状多孔金属与阳极配置满足一定角度时 ,实现阴极表观电流密度恒定 ,镍的结晶细致 .这一工作为电沉积法制备多孔金属的在线控制提供了理论依据 .
【Abstract】 In order to prepare the continuous porous metal by electrodeposition, a mathematical model of continuous electrodeposition of strip porous metal under steady state was deduced,based on the transition from time variable to location variable.Furthermore the expression of apparent distribution for current density was derived. This relationship was verified experimentally from the preparation of porous nickel. When the angle between porous metal strip and anode configuration conformed to the same angle the apparent current density could be kept constant, and nickel crystal was compact.This work provided the theoretical foundation of on-line control in preparing porous metal by electrodeposition.
【Key words】 porous metal; apparent resistance; continuous electrodeposition; current density;
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2004年07期
- 【分类号】TM912.2
- 【下载频次】144