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红色Y2O2S:Eu3+磷光材料的沉淀法制备和发光性能研究

Preparation and Characterization of Y2O2S:Eu3+ Phosphors by Co-precipitation Method

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【作者】 杨志平刘冲郭智冯建伟杨勇李兴民

【Author】 YANG Zhi-ping, LIU Chong, GUO Zhi, FENG Jian-wei, YANG Yong, LI Xing-min (College of Physics Science and Technology, Hebei University, Baoding 071002, China)

【机构】 河北大学物理科学与技术学院河北大学物理科学与技术学院 河北保定 071002河北保定 071002河北保定 071002

【摘要】 用沉淀法制备了Eu3+掺杂的Y2O2S磷光材料,测量并研究了掺杂不同物质的量的Eu3+离子的Y2O2S磷光材料的发射谱和激发谱.发射光谱对应了Eu3+离子5DJ(J=0,1,2,3)-7FJ(J=0,1,2,3,4)的特征发射,激发光谱主峰对应260,345,468,540nm等,余辉时间(到人眼的最小亮度分辨率0.32mcd/m2)可达1h以上.

【Abstract】 Synthesis of the Eu3+-activated Y2O2S by Co-precipitation method was presented. The crystalline phases by direct sintering method and Co-precipitation method were investigated. The excitation spectra and emission spectra of Y2O2S phosphors doped with different Eu3+ molar ratio were measured. The main emission peaks ascribed to Eu3+ ions transition from ()5DJ(J=0,1.2)to ()7FJ(J=0,1,2,3,4) were found. The main excitation peaks includes 260 nm, 345 nm, 468 nm, 540 nm etc. The afterglow time was over 1 hour in the light perception of the dark-adapted human eye (0.32 mcd/m2).

【关键词】 长余辉Y2O2S:Eu3+沉淀法
【Key words】 long afterglowY2O2S:Eu3+Co-precipitation method
【基金】 河北科学技术发展项目(51215103b)
  • 【文献出处】 河北大学学报(自然科学版) ,Journal of Hebei University(Natural Science Edition) , 编辑部邮箱 ,2004年06期
  • 【分类号】O482.31
  • 【被引频次】16
  • 【下载频次】227
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