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阻抑动力学光度法测定痕量苯胺
Inhibitory kinetic spectrophotometric determination of trace aniline
【摘要】 在pH4.5邻苯二甲酸氢钾-氢氧化钠缓冲溶液存在下,痕量苯胺对高碘酸钾氧化孔雀绿褪色反应有强烈的抑制作用,据此建立了阻抑动力学光度法测定痕量苯胺的新方法。方法检出限为0.38μg/L,测定范围为0.0~9.2μg/L。此法用于废水中苯胺的测定,结果令人满意。
【Abstract】 In the presence of potassium biphthalate-sodium hydroxide buffer solution at pH4.5 ,trace aniline in-hibitsstrongly the fading reaction of malachite green by oxidizing with potassium permanganate.Based on thisstudy ,a novel inhibitory kinetic-spectrophotometric method hasbeen developed for the determination of trace aniline.The experimental resultsshow that the detection limit for aniline is0.38μg/L ,the linear range of the determination is0.0~9.2μg/L ,The method hasbeen applied to the determination of trace aniline in wastewater with satisfactory results.
【关键词】 阻抑;
动力学光度法;
孔雀绿;
苯胺;
【Key words】 inhibitory; kinetic-spectrophotometric method; malachite green; aniline;
【Key words】 inhibitory; kinetic-spectrophotometric method; malachite green; aniline;
- 【文献出处】 工业水处理 ,Industrial Water Treatment , 编辑部邮箱 ,2004年01期
- 【分类号】O657.3
- 【被引频次】3
- 【下载频次】86