【摘要】 对苯二酚与 2 硝基 5 ,10 ,15 ,2 0 四苯基卟啉 1及其铜 (Ⅱ ) 2、镍 (Ⅱ ) 3、锌 (Ⅱ ) 4等金属配合物直接加热反应 ,分别制得 2 (2 ,5 二羟苯基 )四苯基卟啉 1′(81% )及相应金属配合物 2′(71% ) ,3′(6 1% ) ,4′(40 % )。它们的结构由IR ,MS ,UV及1 HNMR ,2D NMR等确定。发现对苯二酚通过碳 碳键与卟啉的吡咯环直接相连 ,氢醌与卟啉环趋于共平面 ,其中一个羟基位于卟啉环的去屏蔽区 ,H原子的核磁位移向低场移动 (δ =7 5 2 ) ,另一个则处于中位苯环的屏蔽区 ,H原子的核磁位移为δ =4 18;氢醌环上的质子也表现出不同的核磁位移 ,其中 6位上H的位移值为δ =4 93,明显向高场位移。更多还原

【Abstract】 2-(2,5-dihydroxyphenyl) tetraphenylporphrin 1′, 2 (2,5 dihydroxyphenyl) tetraphenylporphyrinato Cu(Ⅱ)2′, Ni(Ⅱ)3′ and Zn(Ⅱ)4′ were synthesized by direct reaction of 2 nitro 5,10,15, 20 tetraphenylporphrin 1 or its metallic complexes 2, 3, 4 with hydroquinone under heating without solvent. The yields were about 81%, 71%, 61% and 40% respectively for 1′, 2′, 3′ and 4′. Their structures were determined by 1 H NMR, 2D NMR, IR, MS and UV Vis spectra. It is shown that the hydroquinone connects with pyrrole ring through carbon carbon bond, and is located in the same plane of porphyrin. One of the hydroxy group of hydroquinone is located in the deshield area of porphyrin and its proton shift occurs downfield at δ =7 52. Another one is located in the shield area of meso benzene, and the proton shift occurs upfield at δ =4 18. Also the 6 proton shift of hydroquinone occurs upfield at δ =4 93.更多还原