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有机化合物ZnTBP/CA/PhR的非线性光吸收谱测定

Nonlinear Optical Absorption Characteristics of a Novel Organic Material ZnTBP/CA/PhR

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【作者】 李潞瑛赵有源于世瑞郑锐之

【Author】 LI Lu-ying,ZHAO You-yuan,YU Shi-rui,ZHENG Rui -zhi Department of Optical Science and Engineering,State Key Lab of Advanced Photon ic Materials and Devices,Fudan University,Shanghai 200433,China

【机构】 复旦大学光科学与工程系复旦大学光科学与工程系 先进光子学材料与器件国家重点实验室上海200433先进光子学材料与器件国家重点实验室上海200433

【摘要】 测定了新型光功能有机材料锌 四苯并卟吩 巴豆酸 苯氧树脂 (Zn Tetrabenzoporphin CrotonicAcid/PhenoxyResin ,简称ZnTBP/CA/PhR)体系薄膜样品在可见光范围内的吸收谱 ,定点测量了其主要吸收谱带在激光作用下的变化情况 ,实验观察到此种材料显著的饱和及反饱和吸收现象 ,还首次观察到它的再反饱和过程。文章定性分析了变化过程中的物理机制 ,讨论了ZnTBP/CA/PhR的非线性吸收特性在光子学领域的一些应用

【Abstract】 The measurement of optical absorption spectrum i n visible light range of a novel organic material Zn-tetrabenzoporphin-croto nic acid/phenoxy resin (ZnTBP/CA/PhR) is reported in this paper. The nonlinea r absorption property of the sample illuminated by lasers with different wavel engths was studied. And the absorption alteration and kinetic process of the ma jor spectrum bands were observed. The saturation absorption (SA) and reverse saturation absorption (RSA) appeared as the input fluence increased,and re-reverse saturation absorption process of the material was demonstrated in the experiment. These properties occurred in a broad range of visible sp ectrum. The paper qualitatively analyses the physical mechanism during the wh ole course. Based on the nonlinear absorption characteristics,we showed some applications in photonics field of ZnTBP/CA/PhR.

【基金】 国家自然科学基金(698880 1,1 98340 30 )资助项目
  • 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2004年03期
  • 【分类号】O657.3
  • 【被引频次】1
  • 【下载频次】45
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