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阻抑-催化褪色光度法测定痕量F~-的研究
Determination of trace fluoride by inhibition-catalysis discoloring spectrophotometry
【摘要】 在盐酸介质中,F-能明显地阻抑铁(Ⅲ)催化过氧化氢还原亮绿SF的褪色指示反应,据此建立了测定痕量F-的阻抑 催化动力学光度分析方法。该方法测定F-的线性范围为0.0~5.4mg L,检出限为3.8×10-6g L,已应用于测定自来水中微量氟。
【Abstract】 In hydrochloric acid medium, trace fluoride essentially inhibited the light green SF descolorization reaction with H2O2 catalyzed by Fe(Ⅲ). Based on this, an inhibition kinetic spectrophotometric method for the determination of trace fluoride was established. The linear range were 0~5.4 mg/L with a detection limit of 3.8×10-6 g/L for fluoride. This method was used to determine trace fluoride in tap water with satisfactory results.
【关键词】 氟化物;
亮绿SF;
铁(Ⅲ);
催化光度法;
【Key words】 Fluoride; Light green SF; Fe(Ⅲ); Catalytic spectrophotometry;
【Key words】 Fluoride; Light green SF; Fe(Ⅲ); Catalytic spectrophotometry;
- 【文献出处】 分析试验室 ,Analytical Laboratory , 编辑部邮箱 ,2004年05期
- 【分类号】O657.3
- 【被引频次】8
- 【下载频次】104