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ZnO/聚苯胺复合膜的制备和性能表征

Preparation and Characterization of ZnO/PANI Composite Film

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【作者】 黄怀国陈景河邹来昌周剑章吴玲玲林仲华

【Author】 Huang Huaiguo 1, Chen Jinghe 1, Zou Laichang 1, Zhou Jianzhang 2, Wu Lingling 2, Lin Zhonghua 2* (1 Xiamen Zijin Science and Technology Co , LTD , Xiamen 361006, China; Fujian Zijin Research Institute of Mining and Metallurgy, Fujian Zijin Mining Industry Co ,LTD , Shanghang 364200,China; 2 State Key Laboratory for Physical Chemistry of the Solid Surface, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen 361005, China)

【机构】 厦门紫金科技股份有限公司厦门大学固体表面物理化学国家重点实验室厦门大学固体表面物理化学国家重点实验室 福建厦门361006福建厦门361006化学系物理化学研究所福建厦门361005福建厦门361005

【摘要】 采用电化学组装法 (ECA)和溶胶 凝胶法 (sol gel)的联用技术在对胺基苯硫酚 (PATP ,ρ aminothiophenol) Au电极上制备ZnO 聚苯胺(PANI ,polyaniline)复合膜 ,并用TEM ,SEM ,XPS等对ZnO溶胶和ZnO PANI复合膜进行表征。同时还利用紫外 可见吸收光谱、荧光光谱和光电流谱研究了ZnO胶体、ZnO微粒膜和ZnO PANI复合膜的性能。结果表明 ,ZnO PANI复合膜具有优良的发光性能和光电化学转换效率 ,可作为发光纳米材料和处理含有甲基橙的废水

【Abstract】 A ZnO/PANI composite film on PATP/Au was prepared by electrochemical assembly and sol gel technique TEM, SEM, XPS et al were used to characterize the ZnO sol and ZnO/PANI composite film The property of ZnO sol, ZnO particulate film and ZnO/PANI composite film were also studied by UV/Vis absorbance spectra, fluorescence spectra and spectra of photocurrent The results show that the ZnO/PANI composite film has excellent luminescent performance and high photoelectrochemical conversion efficiency, which can be industrially used for luminescent nanomaterials and treating wastewater containing methyl orange

【基金】 国家自然科学基金 ( 2 983 3 0 60 ,2 0 0 2 3 0 0 1,2 0 173 0 44 ) ;福建省青年科技人才创新项目 ( 2 0 0 1J0 3 1) ;教育部科技研究( 99177)资助项目
  • 【文献出处】 稀有金属 ,Chinese Journal of Rare Metals , 编辑部邮箱 ,2003年01期
  • 【分类号】TB43
  • 【被引频次】18
  • 【下载频次】354
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