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苍白秤钩风中脱皮甾酮类化学成分的研究(英文)
ECDYSTEROIDS FROM THE STEMS OF DIPLOCLISIA GLAUCESCENS
【摘要】 从中国广西药用植物苍白秤钩风 (Diploclisiaglaucescens)藤茎的 95 %乙醇提取物中分离得到 5个脱皮甾酮类化合物 ( 1 5 )。通过NMR、MS以及化学沟通等方法分别将其结构鉴定为 paristeroneC 2 0 ,2 2 monoacetonide( 1) ,paristerone( 2 ) ,ecdysterone( 3) ,makisteroneC( 4 )和capisterone( 5 )。化合物 1为首次从自然界分得的天然产物 ,2 ,4 ,5亦为首次从该植物中分得
【Abstract】 Five ecdysteroids were isolated from the EtOH extract of the stems of Diploclisia glaucescens. Their structures were identified as paristerone 20,22 monoacetonide(1),paristerone(2),β ecdysterone(3),makisterone C(4)and capitasterone(5),respectively,on the basis of chemical and physical evidence.This is the first report of paristerone 20,22 monoacetonide isolated from natural source.Compounds 2,4,and 5 were also isolated for the first time from D.glaucescens .
【Key words】 Menispermaceae; Diploclisia glaucescens; ecdysteroid; paristerone 20,22 monoacetonide; paristerone; ecdysterone; makisterone C; capitasterone;
- 【文献出处】 天然产物研究与开发 ,Natural Product Research and Development , 编辑部邮箱 ,2003年02期
- 【分类号】O629
- 【被引频次】16
- 【下载频次】191