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西湖底泥对多环芳烃(菲)的吸附性能

Sorption Properties of PAH(Phenanthrene)on Sediment in West Lake

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【作者】 陈华林; 陈英旭; 沈梦蔚;

【Author】 CHEN Hua-lin 1,2 ,CHEN Ying-xu 1 ,SHEN Meng-wei 1 (1.Department of Environmental Engineering,Zhejiang University,Hangzhou 310029,China;2.Department of Environmental Protection,Sichuan Agricultural U niversity,Ya ’ an 625014,China)

【机构】 浙江大学环境工程系; 浙江大学环境工程系 浙江杭州310029; 四川农业大学环境保护系; 四川雅安625014; 浙江杭州310029; 浙江杭州310029;

【摘要】 采用现场采样、室内分析方法,研究了菲在西湖底泥中的吸附/解吸行为。结果表明,菲在西湖底泥中的吸附和解吸速率都较快,均能在8h内达到平衡。菲的吸附等温线为“S”形,能较好地符合Freundlich方程,说明西湖底泥有不均匀的外表面。其连续吸附/解吸曲线为阶梯形,有明显的不可逆吸附现象,是由于底泥中高含量的有机质造成的。

【Abstract】 Sorption /desorption properties o f phenanthrene on sediment in West Lake were studied.Both sorption and desorption can reach equilibriumin less than 8hour s.Under the conditions of the presen t experiment,the sorption of phenan threne on sediment was characterized by"S"isothermand may be well described by Freundlich equation.It was reflected that there was symmetrical surface in the sediment.It was found that the cu rves of multi -step sorption /desorp tion experiments were step -wise and phenanthrene irre-versibly adsorbed onto the sediment .It may be explained that the irreversible sorption was caused by the high content of organic matters in the sediment.

【关键词】 多环芳烃; 菲; 底泥; 吸附;
【Key words】 polycyclic aromatic hydrocarbon(PAH); phenanthrene; sediment; sorption;
【基金】 杭州市环保局资助项目
  • 【文献出处】 农业环境科学学报 ,Journal of Agro-environmental Science , 编辑部邮箱 ,2003年05期
  • 【分类号】X524
  • 【被引频次】34
  • 【下载频次】459
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